The Electrical Conductivity of a Mixture of Both Symmetrical and Unsymmetrical Complexes in Methanol At 25 °C

We have measured the electrical conductivity of a mixture of both symmetrical and unsymmetrical complexes: {[Ni(en)3](N03)2} + {[Co(en)2Cl2]Cl} in methanol at 298K. The results are analysed using Lee-Wheaton equation. The equivalent conductivities have been compared with the experimental values at the best-fit values of (R) and they are found to be in a good agreement. Besides, we have calculated the ionic concentration, activity coefficient, transport number for each ion present in the solution.